I have no idea what I've done but it seems to be working just in time for me to go to sleep for work tomorrow
I shall have another pop at it tomorrow and it probably won't work again being as there's no rhyme nor reason to what I have done.
Camtasia didn't seem to work on its own, same issue as the other recorders (very nice though).
So I installed that Maxifier program and it does have some options that seem like they might help related to fitting the window to the screen rather than full screening it though I can't remember which option I'm currently using as it doesn't tick the option you've selected.
I also fear that if I close Media Center and reopen it that it won't automatically use maxifier in the correct setting, but I think for the purposes of the demo I can probably work around it.
Bonkers. For anyone else scouring the web for a way of demoing media center in full screen I shall report back tomorrow when I've finally got it working properly.
-P